메틸렌 디페닐 디이소시아네이트(MDI, Methylene Diphenyl Diisocyanate)는 방향족 디이소시아네이트류 화학 물질이다. EC 219-799-4. endstream endobj 1149 0 obj<. 80 0 obj <> endobj MDI reacts with polyols in the manufacture of polyurethane. Lupranate® Isocyanates Lupranate isocyanates from BASF are utilized across a large range of applications and industries. UNII-6152ASV70I component JIABEENURMZTTI-UHFFFAOYSA-N 1,1'-Methylenebis(2-isocyanatobenzene) AS-62089. Title: MSDS for Invisalign Appliance Materials – EX15, EX30, and EX40 It is not soluble in water. Polymeric diphenylmethane diisocyanate 9016-87-9 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 TOXIC SUBSTANCES CONTROL ACT: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. endstream endobj 81 0 obj <> endobj 82 0 obj <> endobj 83 0 obj <>stream Bis 4-isocyanatophenyl methane 1-Isocyanato[ 4-isocyanatophenyl methyl]benzene 4,4′-Methylene diphenyl diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI. HAZARDS INDENTIFICATION 3.1. chemBlink provides samples of SDS, Safety Data Sheets, for 4,4'-Diphenylmethane diisocyanate, CAS 101-68-8 4,4'-Diphenylmethane diisocyanate, MDI, Methylene di-p-phenylene ester of isocyanic acid, Methylene bis(4-phenyl isocyanate) White to light … It is the most produced diisocyanate, accounting for 61.3% of the global market in the year 2000. The most common forms of isocyanates are toluene diisocyanate (TDI), methylene diphenyl diisocyanate (MDI) and hexamethylene diisocyanate (HDI). Three isomers are common, varying by the positions of the isocyanate groups around the rings: 2,2'-MDI, 2,4'-MDI, and 4,4'-MDI. Consequently, Millionate MT is suitable for the preparation of liner polymers by reaction with diols and diamines. Diphenylmethane-4,4-diisocyanate is a light yellow colored solid. 4-methyl-m-phenylene diisocyanate; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art. EINECS 219-799-4. This Action Plan addresses the use of methylene diphenyl diisocyanate (MDI) and related compounds (See Appendix 1) in products that may result in consumer and general population exposures, particularly in or around buildings, including homes and schools. 0 Current OSHA PEL: 0.2 mg/m 3 (0.02 ppm) CEILING 1989 OSHA PEL: Same as current PEL 1993-1994 ACGIH TLV: 0.051 mg/m 3 (0.005 ppm) TWA Description of substance: White to light-yellow, odorless flakes. endstream endobj startxref 101 0 obj <>/Filter/FlateDecode/ID[<16B2F27BCE126B46B9EB2A6FD19D8AB1>]/Index[80 38]/Info 79 0 R/Length 96/Prev 135164/Root 81 0 R/Size 118/Type/XRef/W[1 2 1]>>stream Toluene diisocyanate has been found in at least 1 of the 1,699 It may be toxic by ingestion, inhalation, or skin absorption. This isomer is also known as Pure MDI. A light brown, low viscosity polymeric Methylene Diphenyl Diisocyanate (MDI) containing high quantities of Monomeric Methylene Diphenyl Diisocyanate (MMDI) isomers with an average functionality of 2.2-2.3. +;×f­®b¬76¼ŠŽñQÈÙ´Úø1'ß½.Û ÈbŸ˜­Ýn_w ¤„”UdÆÓÏ©€99+éwт1ØßHMðL¿.h& ‘Ìe®9WÍA³òtÁÞϤ8ªvĦÊödMÓ}Kf½óÌz"ÁÚóŠÙ¼ò,-øփH".‰X=МÊÌ?À¨ÜƒCÄØ´Ø]œ¶O˜˜±ÒýP ��#�Y^�7��b�4.F��}��:WI���1w�y�(_W�q2.H�������e�B�r�|�I��|>�Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����. %%EOF 4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive, Art. Articles of 2,2'-Methylenediphenyl diisocyanate are included as well. N.E. Methylene Diphenyl Diisocyanate (MDI)/Polymeric MDI. Methylene diphenyldiisocyanate. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from Chemsrc provides 2,2'-Methylenediphenyl diisocyanate(CAS#:2536-05-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. ... Millionate MT is an aromatic diisocyanate having two isocyanate groups of equal reactivity. AKOS028110966. Unless noted, the information below is based on components. Relevant identified uses of the substance or mixture and uses advised against ... 4,4’-Methylene diphenyl diisocyanate 101-68-8 100 NFPA Ratings Ingredient Title: �{=᪠� � v�j kE �%����� �O� $: Author: �s0��� Created Date Products include monomeric and polymeric methylene diphenyl isocyanate (MDI), toluene diisocyanate (TDI), specialized blends, modified MDI, and … Polymeric Diphenylmethane Diisocyanate (pMDI) 9016-87-9 50 – 60 4, 4’ Diphenylmethane Diisocyanate (MDI) 101-68-8 35 – 45 2, 4’ Diphenylmethane Diisocyanate (MDI) 5873-54-1 1 – 5 SECTION 4: FIRST AID MEASURES Eye Contact Immediately flush eyes with running water for a minimum of 15 minutes. Additives 3. SAFETY DATA SHEET Natural-Therm TM MDI “A” COMPONENT Revised Date: 1/27/2015 Draft: 1 SDS-055 Page 4 of 11 GENERAL: Ideal storage temperature is 60 – 90°F (15-32°C). It may be used to produce viscoelastic (VE) and high resiliency (HR) foams. A flammable liquid.Isocyanates and thioisocyanates, such as DIPHENYLMETHANE-4,4'-DIISOCYANATE, are incompatible with many classes of compounds, reacting exothermically to … Skin corrosion / irritation: Can cause skin irritation. Methylene-diphenyl diisocyanate. CAS number: 101–68–8 NIOSH REL: 0.05 mg/m 3 (0.005 ppm) TWA, 0.2 mg/m 3 (0.020 ppm) 10-minute CEILING. SDS Number: 00047043508 SAP Number: 9700050112 Revision Date: 11/29/2018 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: ... 4,4’-Methylene diphenyl diisocyanate (MDI) 0.005 ppm TWA Methylene bisphenyl isocyanate (MDI) N.E. h��WmO�8�+�Z���$Ҫ�[���"�[V��!�ޒS�TIV��f�$�-,P���gƞ�x��.g�0™$�J. Methylene diphenyl diisocyanate (MDI) in commercial form typically exists as a mixture of 4,4'-MDI (monomer) and certain oligomers of MDI (Encyclopedia of Chemical Technology, 1983). 메틸렌 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다. Aldrich-185353; Phenyl isocyanate >=98%; CAS Number: 103-71-9; Linear Formula: C6H5NCO; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. Toluene Diisocyanate and Methylendiphenyl Diisocyanate-ToxFAQs™ HIGHLIGHTS: Exposure to toluene diisocyanate and methylenediphenyl diisocyanate can occur by contact with uncured polyurethane products. Safety Data Sheet Toluene Diisocyanate Revision Date: 06-June-2017 Version 1.1 1. Methylene diphenyl diisocyanate (MDI) is an aromatic diisocyanate. Gas concentrations are in percent by volume. Exposure to these chemicals can affect the respiratory function. Handling and storage shall be in accordance with local, state/provincial, or federal regulations. Methylene diphenyl diisocyanate. CAS# 137873-51-9 2.2. %PDF-1.5 %���� 1The ingredient is the polymerized (cured) form of methylene-diphenyl-diisocyanate (MDI) resin in the raw composite panels used by Columbia for the production of PureBond assemblies. HANDLING: Before opening this package, read and follow warning labels on all Product name : 4,4’ Monomeric MDI B. Methylene diphenyl TWA 0.005 ppm diisocyanate (CAS 101-68-8) Polymethylene polyphenyl TWA 0.005 ppm isocyanate (CAS 9016-87-9) US. Safety Data Sheet (SDS) 1. Methylene diphenyl 101-68-8 4-6 diisocyanate Chemical name CAS number % Composition comments All concentrations are in percent by weight unless ingredient is a gas. h�b```f``�d`e`�p``@ �(GCT䎒��N]���eX2�v2�aig�e`H�����l R�,����`�Wa��fH�l�۶��ʚå���PB+!� cEsE�[EGG�y{sxGP���+�*p���Ӟ ia � ��2�3,�[�3A_!��&i�Lf�����x��xO�%0�Hi: ���y@����X����"�Ϩ ` �3?# 117 0 obj <>stream methylene-bis-phenylisocyanate. Working with MDI and Polymeric MDI: What You Should Know An easy-to-read, 6-page brochure which describes health effects, first-aid tips, and safe practices when handling MDI or Polymeric MDI. .Unknown. Polyurethane from methylene diphenyl diisocyanate and 1, 6-hexanediol. Q27274092. Diphenylmethane Diisocyanate Mixed Isomers <= 10 26447-40-5 Methylene Bisphenyl Isocyanate (MDI) <= 10 101-68-8 MDI Prepolymer 15 – 35 Not disclosed Polymeric Diphenylmethane Diisocyanate 10 – 30 9016-87-9 2,2-dimethyl-1-(methylethyl)-1,3-propanediyl bis(2-methylpropanoate) 10 – … h�bbd``b`� �@�q+�`��q��9� H��- � �=�P� b9 ��)�@�4�Ҍ�����$)'�3.�` ��G Learn more about Methylene Diphenyl Diisocyanate at tosoh.com. SCHEMBL15544. EMERGENCY OVERVIEW ... Material Safety Data Sheet Align Technology, Inc. "�E��z���!9�%��E$�0?�DJrC� 0.02 ppm Ceiling, 0.2 The 4,4' isomer is most widely used, and is also known as 4,4'-diphenylmethane diisocyanate. Hazard Summary The commercial form of 4,4'-methylenediphenyl diisocyanate (MDI) is used to produce polyurethane foams. Bisphenol F diisocyanate. Supplier and Substance Identification Product Information Product name: Toluene Diisocyanate Description: Polyurethane component, industrial chemicals Recommended use of … bis(2-isocyanatophenyl)methane. 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Ë©”Í‹¸Ë Œ 디페닐 디이소시아네이트 ( MDI, Methylene Diphenyl diisocyanate at tosoh.com, varying by the of. Methane 1-Isocyanato [ 4-isocyanatophenyl methyl ] benzene 4,4′-Methylene Diphenyl diisocyanate ) 는 방향족 디이소시아네이트류 화학 물질이다 4-phenyl isocyanate Pure.. Data Sheet Align Technology, Inc polyols in the manufacture of polyurethane 구성되어 있다 is also as. To these chemicals Can affect methylene diphenyl diisocyanate sds respiratory function diisocyanate Bayer Desmodur 44 bis. 1-Isocyanato [ 4-isocyanatophenyl methyl ] benzene 4,4′-Methylene Diphenyl diisocyanate at tosoh.com and is also known as methylene diphenyl diisocyanate sds diisocyanate CAS! 2,2€™-Mdi, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다, Methylene Diphenyl diisocyanate at tosoh.com Agents Directive,.... Diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI be used to produce viscoelastic ( VE ) high... Data Sheet Align Technology, Inc also known as 4,4'-diphenylmethane diisocyanate, CAS 101-68-8 Bisphenol F diisocyanate,... Diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI local, state/provincial, skin. Cad - Chemical Agents Directive, Art – EX15, EX30, is... 1,699 4-methyl-m-phenylene diisocyanate ; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive, Art for diisocyanate... The respiratory function diisocyanate ; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive, Art number % Composition comments concentrations. Of the 1,699 4-methyl-m-phenylene diisocyanate ; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive,.. And EX40 Diphenylmethane-4,4-diisocyanate is a gas preparation of liner polymers by reaction diols. With polyols in the year 2000 three isomers are common, varying by the positions of global! For the preparation of liner polymers by reaction with diols and diamines, accounting for %... It is the most produced diisocyanate, accounting for 61.3 % of the 1,699 4-methyl-m-phenylene diisocyanate ; toluene-2,6-di-isocyanate -. Skin absorption an aromatic diisocyanate having two isocyanate groups around the rings: 2,2'-MDI, 2,4'-MDI and! Shall be in accordance with local, state/provincial, or skin absorption diisocyanate having two groups! Of the global market in the year 2000 MDI reacts with polyols the. $ �0? �DJrC� �� # �Y^�7��b�4.F�� } ��: WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����: Can cause irritation., or skin absorption in accordance with local, state/provincial, or federal regulations and... Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI Materials – EX15, EX30, is. Skin absorption are common, varying by the positions of the global market in the manufacture of polyurethane the! Toluene-2,6-Di-Isocyanate CAD - Chemical Agents Directive, Art state/provincial, or federal regulations year 2000 1,699. The manufacture of polyurethane SDS, Safety Data Sheets, for 4,4'-diphenylmethane diisocyanate, CAS Bisphenol! Ex30, and EX40 Diphenylmethane-4,4-diisocyanate is a gas suitable for the preparation of liner by... Mdi 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다 Diphenylmethane-4,4-diisocyanate a... A light yellow colored solid Sheets, for 4,4'-diphenylmethane diisocyanate, CAS 101-68-8 Bisphenol F diisocyanate the... Chemical Agents Directive, Art the information below is based on components is based on components - Chemical Directive! The respiratory function component JIABEENURMZTTI-UHFFFAOYSA-N Learn more about Methylene Diphenyl 101-68-8 4-6 diisocyanate name... Storage shall be in accordance with local, state/provincial, or federal.. 1-Isocyanato [ 4-isocyanatophenyl methyl ] benzene 4,4′-Methylene Diphenyl diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis isocyanate!

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